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Solubility

Solubility refers to the ability of a substance (solute) to dissolve in a solvent to form a homogeneous solution. It depends on temperature, pressure, and the nature of the solute and solvent.

Factors Affecting Solubility

  1. Nature of Solute and Solvent

    • “Like dissolves like”: Polar solutes dissolve in polar solvents; nonpolar solutes dissolve in nonpolar solvents.
  2. Temperature

    • Most solids: Solubility increases with temperature
    • Most gases: Solubility decreases with temperature
  3. Pressure (mainly affects gases)

    • Higher pressure increases gas solubility in liquids (Henry’s Law: S = kP)
  4. Common Ion Effect

    • Presence of ions already in solution reduces solubility of a salt due to Le Chatelier’s principle.

Saturation

  • Unsaturated: Contains less solute than maximum; more can dissolve
  • Saturated: Contains maximum solute at given conditions; dynamic equilibrium exists
  • Supersaturated: Contains more solute than equilibrium; unstable, may crystallize spontaneously

Importance

  • Predicting precipitation reactions in chemistry
  • Designing pharmaceutical formulations and solutions
  • Understanding environmental processes such as gas absorption in water

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